无金属光催化剂催化过氧化氢生产的研究进展Research Progress in Metal-free Photocatalysts for Hydrogen Peroxide Production
次超,赵强,刘雪贞,刘江宁,武鲜凤,吴旭
摘要(Abstract):
过氧化氢(H_2O_2)是一种绿色强效氧化剂,能够在温和条件下氧化液体介质中的多种有机和无机基质,与化学计量氧化剂相比,其活性氧含量高,且只释放H_2O和O_2作为最终产物,具有环保高效的独特优势。相对于传统的蒽醌产H_2O_2工艺,光催化过程具有低耗、环保、安全等的优势。无金属光催化剂由于其合成简单、成本低、环境友好、生物相容性高等的特征成为光催化产H_2O_2的理想光催化剂之一。文章论述了无金属光催化剂近年来在光催化产H_2O_2领域最新进展。主要包括:光催化产H_2O_2的基本机理及过程以及石墨氮化碳(g-C_3N_4)、共价有机框架(COFs)、有机聚合物主要无金属光催化剂的特征及其在光催化产H_2O_2重要进展。讨论了现阶段光催化产H_2O_2研究中遇到的问题和挑战,并提出一些见解和方法,特别是在光催化产H_2O_2机理过程、催化剂稳定性和H_2O_2分离、光催化产H_2O_2速率提升方面。该综述旨在促进光催化产H_2O_2的发展及应用。
关键词(KeyWords): 光催化;无金属光催化剂;过氧化氢
基金项目(Foundation): 国家自然科学基金(51978436)
作者(Author): 次超,赵强,刘雪贞,刘江宁,武鲜凤,吴旭
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