N-甲基-3-溴咔唑与β-环糊精包结作用研究Study on Inclusion Complex of N-Methyl-3-Bromocarbazole with β-Cyclodextrin
李红晋,高竹青,张苏琳,张星明
摘要(Abstract):
运用荧光光谱法,通过考察N-甲基-3-溴咔唑在水、乙醇、β-环糊精、甲基-β-环糊精、羟丙基-β-环糊精、γ-环糊精等溶液中的荧光光谱及荧光强度的变化,认为N-甲基-3-溴咔唑与β-环糊精可能的包结方式为轴向包结,而且光谱特性与微环境极性有很大的关系。
关键词(KeyWords): 荧光光谱法;N-甲基-3-溴咔唑;环糊精;包结物;微环境
基金项目(Foundation): 山西省高校科技研究开发项目(20051279)
作者(Author): 李红晋,高竹青,张苏琳,张星明
参考文献(References):
- [1]SASAK I K J,CHR ISTIAN S D,TUCKER E E.Use of visib le spectral d isp lacem ent m ethod to determ ine the concentration ofsunfactants in aqueous solution[J].J Colloid Interface Sc i,1990,134(2):412-416.
- [2]LI S,PURDY W C.Cyc lodextrins and the ir app lications in analytical chem istry[J].Chem.Rev,1992,92:1457-1470.
- [3]GUO W,FUNG B M,Christian S D.NMR Study of cyc lodextrin inc lusion of fluorocarbon surfactants in solution[J].Lang-mu ir,1992,(8):446-451.
- [4]CROMWELLW C,Bystrom K,E ftinkM R,Cyc lodextri-nadam antanecarboxlate in lusion comp lexes stud ies of variation in cavitysize[J].J.Phys Chem,1985,89:446-451.
- [5]SATAKE I,YOSHH IDA S,HAYAKAWA K,et al,Conductom etric detem ination of the assec iation constants ofβ-cyc lodextrinsw ith anph iph ilic ions[J].B lun Chem Soc Jpn,1986,59(12):3991-3993.
- [6]LEGRAND M,ROUG IER M J著;陈荣峰译.旋光谱和圆二色谱[M].开封:河南大学出版社,1990.
- [7]劳文剑,尤进茂,于兆文,欧庆瑜.溴代咔唑的合成及正相高效液相色谱分离[J].化学试剂,2000,22(5):260-261.
- [8]陈国珍.荧光分析法[M].北京:科学出版社,1990,78.
- [9]任锋,朱亚先,鹿贞彬,慕俊泽,张勇.荧光光谱法研究芘与β-环糊精、羟丙基β-环糊精的相互作用[J].厦门大学学报(自然科学版),2004,43(3):372-375.
- [10]SBAIM,LYAZID I S A it,LERNER D A,CASTILLO B del,MARTIN M A.Mod ified-βcyc lodextrins as enhancers of fluores-cence em ission of carbazole alkaloid derivatives[J].Anal.Chem.Acta,1995,303:47-55.